Hello Readers, welcome to your own website to understand each and every topic related to the manufacturing process where we transform complex content into simpler ones. In this article, we are focused to cover the meaning of tempering, advantages, disadvantages, and applications of tempering.


The tempering cycle is a exceptionally basic process, just heat the glass up to well over the change temperature, maintain the glass optically flat, or form it to a shape if required, then consistently cool it so that the temperatures of the top and bottom surfaces are equal, and lower the temperature at the centre plane of the glass, as it cools to below the strain
temperature, then cool it underneath to ambient temperature.

That is the ‘sum total’ of what a decent tempering framework does.

In any case, the following has to be accomplished in order to get the great quality tempered glass.

Exceptionally uniform temperature in the glass as it leaves the furnace and enters the quench.

Fig.1 Transmission electron micrographs of quenched and tempered 300-M steel samples (a) after tempering at 3008C for 2 min, showing cementite plates in a martensite lath, and (b) after tempering at 6008C for 1 min, showing alloy carbides.

Temperature should be well over the Transition Point (567OC).

Temperature well below the Softening Point (710OC).

Keep the glass optically flat while delicate (or form it if required), move it to a quench without losing lot of temperature.

Consistently cool it at a controlled rate to the Transition Point (567OC).

Keep up the cooling rate until well underneath the Strain Point (510OC) and cool it down to a dealing temperature.

The main cycle occurred when the tempering are precipitation and recrystallization of martensite.

Quenched steel has a metastable design. Whenever subjected to heating, the structure becomes nearer to equilibrium.

The speciality of the process just happens only when tempering is
determined by three huge features of quenched steel:

Strong supersaturation of the martensite solid solution.

High density of crystal lattice defects (dislocations, low- and huge angle
boundaries, twin interlayers), and the presence of retained austenite.

The main cycle occurring during tempering of steels is precipitation of martensite accompanied by formation of carbides.

Martensite precipitation may work in three stages depending on the temperature and duration of tempering.

Precipitation of intermediate metastable carbides precipitation and coagulation of cementite.

Retained austenite can precipitate simultaneously.

Inferable from a high density of dislocations in martensite, its substructure is like the base of a work-hardened (deformed) metal.

Subsequently, polygonization and recrystallization can create during tempering.

Supersaturation of the  solution in austenite increases with an increase in the carbon content of steel when carbon steels are tempered.

Because of this, there is lowering of the temperature Ms and transition from massive martensite to plate martensite.

The amount of retained austenite also increases.

Carbon segregation represents the first structural changes that take place during tempering of carbon steels.

The isolated carbon can nucleate heterogeneously at lattice defects or homogeneously in the matrix.

The heterogeneous nucleation of the segregated carbon forms either during quenching or immediately after it.

Flat homogeneous clusters of carbon atoms that are not connected with lattice defects are formed at tempering temperatures below 1008C (2128F).

Their development is because of extensive removals of iron particles and the presence of elastic distortions.

The clusters become larger and their composition is close to Fe4C,  as the tempering temperature is  get increased.

This process depends on carbon diffusion. Metastable e-carbide (Fe2C) is formed above 1008C (2128).

It possesses a hexagonal lattice and appears directly from carbon clusters
when the carbon concentration is increased.

Fig.2 Electron microscopic image of the e-carbide, 50,000.

Metastable e-carbide can also precipitate directly from the solution.

At low temperatures e-carbide precipitates as very fine (10–100 nm) plates or rods.

With an increase in tempering temperature or time, e-carbide particles become coarser.

This carbide precipitates in steels containing a minimum of 0.2% C.

In steel having a high Ms temperature, i.e., all structural steel primary prepares, halfway precipitation of martensite joined by deposition of excess carbide is cultivated during quench cooling in the martensite range. At that point self-tempering of these prepares during their quenching.

The final stage of the carbide formation during tempering is coagulation and spheroidization of carbide.

These processes created intensively starting from the range 350 to 400C (660–750F).

All cementite particles have a spherical shape and undergo coagulation only if when the temperature go above 600C (1112F).

At the second stage of martensite precipitation (150–300C, 300–570F) the answer is exhausted of carbon owing to diffusive development of carbide particles.

But the process proceeds very slowly.

So, the precipitation energy are described by a fast depletion of the a solution in carbon (the timespan decreases as the annealing temperature is increased).

Continuously depletion of the solid solution in carbon stops.

At 300C (570F) about 0.1% C is left in the a solution.

Above this temperature no difference between the lattice of a solution and that of the alpha -Fe is detected.

Below 300C the degree of tetragonality (c=a > 1) is still measurable.

At high temperature above the 408C (750F), the solution becomes completely free of to much carbon and transformation of martensite to ferrite is finished.


In tempering the molten salt, saltpeter, low-melting metals are use as coolant.

In stepwise steel tempering method helps to minimize the internal voltages, warpage and cracks possibility.


In tempering process there is one of main  the disadvantage of this tempering is that cooling in hot environments can’t provide a high cooling rate at 400-600 °C temperature range.


Tempering is utilized to improve (reduce and control) hardness, strength, and durability, while at same time decreases brittleness in completely hardened steel.

Tempering  requires exact time and temperature control during the whole process to arrive at the ideal actual properties for the eventual outcome.\


We have covered all the important concepts related to tempering process. Hope you all are crystal clear with understanding all the concepts mentioned here. If you have any questions please use the comments section to get in touch with us. Till then have fun and always keep reading!


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